Season four of Madam Secretary finds Elizabeth (Téa Leoni) trying to achieve diplomacy despite many global enemies poised against her and new political rivals at home. Henry (Tim Daly) takes on a new role at the CIA, which sometimes puts him at cross-purposes with Elizabeth, both professionally and personally. Also this season, their daughters Stevie (Wallis Currie-Wood) continues with her internship in Russell Jackson's (Željko Ivanek) office and Alison (Kathrine Herzer) goes off to college, press secretary Daisy (Patina Miller) has a baby, and the president’s chief of staff Dmitri (Chris Petrovski) returns.
| Title | Time | Price | ||
|---|---|---|---|---|
| 1 | News Cycle | 43:18 | USD 2.99 | |
| 2 | Off the Record | 43:22 | USD 2.99 | |
| 3 | The Essentials | 43:07 | USD 2.99 | |
| 4 | Shutdown | 43:21 | USD 2.99 | |
| 5 | Persona Non Grata | 43:26 | USD 2.99 | |
| 6 | Loophole | 43:16 | USD 2.99 | |
| 7 | North to the Future | 43:20 | USD 2.99 | |
| 8 | The Fourth Estate | 43:20 | USD 2.99 | |
| 9 | Minefield | 43:21 | USD 2.99 | |
| 10 | Women Transform the World | 43:19 | USD 2.99 | |
| 11 | Mitya | 43:22 | USD 2.99 | |
| 12 | Sound and Fury | 43:20 | USD 2.99 | |
| 13 | Reading the Signs | 43:16 | USD 2.99 | |
| 14 | Refuge | 43:21 | USD 2.99 | |
| 15 | The Unnamed | 43:09 | USD 2.99 | |
| 16 | My Funny Valentine | 43:22 | USD 2.99 | |
| 17 | Phase Two | 43:22 | USD 2.99 | |
| 18 | The Friendship Game | 43:19 | USD 2.99 | |
| 19 | Thin Ice | 43:22 | USD 2.99 | |
| 20 | The Things We Get to Say | 43:15 | USD 2.99 | |
| 21 | Protocol | 43:20 | USD 2.99 | |
| 22 | Night Watch | 43:23 | USD 2.99 | |
| 23 | Madam Secretary, Season 4 (First Look) | 00:32 | Free |
